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- W2024224116 abstract "An approach to concentrate trivalent lanthanide elements into or onto mercury film electrodes supported on rotating disk glassy carbon electrodes in small volumes (≤1000 μL) is described. La3+ was used as a model for the trivalent f-element cations because its standard potential is the most negative. La3+ cathodically sorbed onto or into a preformed Hg film electrode from LiCl. After initial characterizations, Nd3+, Eu3+, Gd3+, Ho3+, and Lu3+ were tested individually and in a mixture. ICPMS analyses demonstrated that these elements could be accumulated cathodically from LiCl solution and stripped anodically in 2% HNO3, both individually and as a mixture. These cations can be electrochemically preconcentrated onto and stripped from the electrode in 5 min, a vast improvement over traditional approaches such as evaporation that require hours to days in some cases." @default.
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- W2024224116 date "2010-06-09" @default.
- W2024224116 modified "2023-10-14" @default.
- W2024224116 title "Preconcentration of Trivalent Lanthanide Elements on a Mercury Film from Aqueous Solution Using Rotating Disk Electrode Voltammetry" @default.
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- W2024224116 doi "https://doi.org/10.1021/ac101180w" @default.
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