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- W2024224587 abstract "Abstract A simple relation exists between the packing density in crystals of short A-DNA duplexes and their global double-helical structure. The volume per nucleotide pair shows a linear inverse correlation with the mean displacement of base pairs from the best straight helix axis. The mean displacement is a measure of major groove depth and varies between - 3.3 Å and −4.9 Å in A-form oligonucleotides analysed in the crystalline state. Since the mean displacement of base pairs from the helix axis determines other helical parameters such as base-pair longitudinal slide, its correlation with crystal packing is of considerable interest. The displacement- packing correlation is very clear for octamer duplexes which crystallize in three different lattices. Longer A-helical fragments sometimes deviate from the rule. It may be speculated whether A- form duplexes not completing a full helical turn are especially prone to distortions due to packing in crystals or arising from intermolecular contacts in solution." @default.
- W2024224587 created "2016-06-24" @default.
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- W2024224587 date "1991-02-01" @default.
- W2024224587 modified "2023-09-24" @default.
- W2024224587 title "A Note on Crystal Packing and Global Helix Structure in Short A-DNA Duplexes" @default.
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- W2024224587 doi "https://doi.org/10.1080/07391102.1991.10507846" @default.
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