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- W2024225746 abstract "For 23 lines from all three fundamental bands of H2S, noble gas broadening coefficients were measured applying a two-channel diode laser spectrometer in pulsed mode. Altogether for 17 lines from the ν1band (3 ≤J″ ≤ 17, 0 ≤Ka″≤ 6), 1 line from the ν2band (J″ = 4,Ka″= 3), and 5 lines from the ν3band (3 ≤J″ ≤ 7, 1 ≤Ka″≤ 7) broadening coefficients γH2S–noble gasfor collisions with helium, neon, argon, krypton, and xenon were determined. The broadening coefficients for lines from different bands with similar rotational quantum numbers are comparable. Within the studied quantum number range, as in the case of collisions with H2S and air, the broadening coefficients show a pronouncedJ″ dependence but noKa″dependence. The values for γH2S–noble gasdecrease strongly with increasing J″. The largest change is observable for collisions with argon and krypton where a decrease in γH2S–noble gasfrom values of about 0.1 to 0.013 cm−1/atm occurs. The broadening coefficients for collisions with different noble gas perturbers for the majority of lines follow the trends γH2S–He> γH2S–Ne, γH2S–Ne< γH2S–Ar, γH2S–Ar< γH2S–Kr, and γH2S–Kr≈ γH2S–Xe." @default.
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- W2024225746 date "1997-07-01" @default.
- W2024225746 modified "2023-10-14" @default.
- W2024225746 title "Noble Gas Broadening in Fundamental Bands of H2S" @default.
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- W2024225746 doi "https://doi.org/10.1006/jmsp.1997.7290" @default.
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