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• W2024229775 abstract "In the unitary-group formulation of quantum chemistry, the spin-projected, configuration-state spaces of quantum chemistry are realized by the irreducible representation spaces (IRS) of the freeon unitary group U(n), where n is the number of freeon orbitals. The Pauli-allowed IRS are labeled by the partitions [λ] = [2(N/2)−s, 12S], where N and S are the particle number and the spin, respectively. The generator-state approach (GSA) to the unitary-group formulation consists of (1) the construction of the overcomplete, nonorthonormal generator basis for each IRS; (2) the Lie-algebraic computation of matrix elements over generator states; (3) the Moshinsky–Nagel construction of the complete, orthonormal Gel'fand basis in terms of the generator basis; and (4) the computation of matrix elements over Gel'fand states in terms of matrix elements over generator states." @default.
• W2024229775 created "2016-06-24" @default.
• W2024229775 creator A5084752404 @default.
• W2024229775 date "1987-07-01" @default.
• W2024229775 modified "2023-09-27" @default.
• W2024229775 title "Spin-free quantum chemistry. XXIII. The generator-state approach" @default.
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• W2024229775 doi "https://doi.org/10.1002/qua.560320108" @default.
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