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• W2024243553 startingPage "342" @default.
• W2024243553 abstract "Thermal energy atom scattering (TEAS) is used to determine the initial sticking probability S0 for dissociative chemisorption of O2 on Ag(111). Mixed beams of He and O2 are used to study S0 as a function of energy of the molecule (MBTEAS). At thermal energies S0 is about 3.5×10−6. It drops to immeasurably low values with increasing energy and rises to about 1×10−5 on further increase of the incident energy (1.6 eV at 45°). S0 seems to scale with En. Two different mechanisms are responsible for sticking. At low energies physisorption-mediated sticking is dominant, and at high energies sticking via an activated precursor prevails. The adsorbed oxygen is removed in a first-order process with a decay time of 1000 s, as determined from the time dependence of the TEAS signal." @default.
• W2024243553 created "2016-06-24" @default.
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• W2024243553 date "1989-07-01" @default.
• W2024243553 modified "2023-09-27" @default.
• W2024243553 title "Dissociative adsorption of O2 on Ag(111)" @default.
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• W2024243553 doi "https://doi.org/10.1016/0009-2614(89)87497-4" @default.
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