Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024253043> ?p ?o ?g. }
- W2024253043 endingPage "3464" @default.
- W2024253043 startingPage "3454" @default.
- W2024253043 abstract "Reactions of the ruthenium complexes [Ru(κ3-tpy)(PPh3)Cl2], [Ru(κ3-tptz)(PPh3)Cl2] and [Ru(κ3-tpy)Cl3] [tpy = 2,2′:6′,2′′-terpyridine; tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine] with diphenyl-(2-pyridyl)-phosphine (PPh2Py) have been investigated. The complexes [Ru(κ3-tpy)(PPh3)Cl2] and [Ru(κ3-tptz)(PPh3)Cl2] reacted with PPh2Py to afford [Ru(κ3-tpy)(κ1-P-PPh2Py)2Cl]+ (1) and [Ru(κ3-tptz)(κ1-P-PPh2Py)2Cl]+ (2), which were isolated as their tetrafluoroborate salts. Under analogous conditions, [Ru(κ3-tpy)Cl3] gave a neutral complex [Ru(κ3-tpy)(κ1-PPh2Py)Cl2] (3). Upon treatment with an excess of NH4PF6 in methanol, 1 and 2 gave [Ru(κ3-tpy)(κ1-P-PPh2Py)(κ2-P,N-PPh2Py)](PF6)2 (4) and [Ru(κ3-tptz)(κ1-P-PPh2Py)(κ2-P,N-PPh2Py)](PF6)2 (5) containing both monodentate and chelated PPh2Py. Further, 4 and 5 reacted with an excess of NaCN and CH3CN to afford [Ru(κ3-tpy)(κ1-P-PPh2Py)2(CN)](PF6) (6), [Ru(κ3-tpy)(κ1-P-PPh2Py)2(NCCH3)](PF6)2 (7), [Ru(κ3-tptz)(κ1-P-PPh2Py)2(CN)]PF6 (8) and [Ru(κ3-tptz)(κ1-P-PPh2Py)2(NCCH3)](PF6)2 (9) supporting hemi labile nature of the coordinated PPh2Py. The complexes have been characterized by elemental analyses, spectral (IR, NMR, electronic absorption, FAB-MS), electrochemical studies and structures of 1, 2 and 3 determined by X-ray single crystal analyses. At higher concentration level (40 μM) the complexes under investigation exhibit inhibitory activity against DNA-Topo II of the filarial parasite S. cervi and 3 catalyses rearrangement of aldoximes to amide under aerobic conditions." @default.
- W2024253043 created "2016-06-24" @default.
- W2024253043 creator A5034434638 @default.
- W2024253043 creator A5035021700 @default.
- W2024253043 creator A5054304542 @default.
- W2024253043 creator A5083797035 @default.
- W2024253043 date "2011-11-01" @default.
- W2024253043 modified "2023-10-17" @default.
- W2024253043 title "Bio-catalysts and catalysts based on ruthenium(II) polypyridyl complexes imparting diphenyl-(2-pyridyl)-phosphine as a co-ligand" @default.
- W2024253043 cites W115074200 @default.
- W2024253043 cites W150764729 @default.
- W2024253043 cites W1532829068 @default.
- W2024253043 cites W157893052 @default.
- W2024253043 cites W1581614904 @default.
- W2024253043 cites W1965575067 @default.
- W2024253043 cites W1965922746 @default.
- W2024253043 cites W1969436685 @default.
- W2024253043 cites W1969509284 @default.
- W2024253043 cites W1970630586 @default.
- W2024253043 cites W1971313723 @default.
- W2024253043 cites W1971481046 @default.
- W2024253043 cites W1973053726 @default.
- W2024253043 cites W1977231720 @default.
- W2024253043 cites W1977935357 @default.
- W2024253043 cites W1980288299 @default.
- W2024253043 cites W1984668192 @default.
- W2024253043 cites W1985842075 @default.
- W2024253043 cites W1987366020 @default.
- W2024253043 cites W1989831408 @default.
- W2024253043 cites W1990781934 @default.
- W2024253043 cites W1991291775 @default.
- W2024253043 cites W2003483394 @default.
- W2024253043 cites W2003909595 @default.
- W2024253043 cites W2005317841 @default.
- W2024253043 cites W2008134598 @default.
- W2024253043 cites W2011094304 @default.
- W2024253043 cites W2011977029 @default.
- W2024253043 cites W2014588550 @default.
- W2024253043 cites W2016408785 @default.
- W2024253043 cites W2017597739 @default.
- W2024253043 cites W2019047089 @default.
- W2024253043 cites W2019310454 @default.
- W2024253043 cites W2025539316 @default.
- W2024253043 cites W2026587618 @default.
- W2024253043 cites W2027492893 @default.
- W2024253043 cites W2027997232 @default.
- W2024253043 cites W2031676888 @default.
- W2024253043 cites W2034507215 @default.
- W2024253043 cites W2037636027 @default.
- W2024253043 cites W2040467271 @default.
- W2024253043 cites W2042062103 @default.
- W2024253043 cites W2048036990 @default.
- W2024253043 cites W2052474694 @default.
- W2024253043 cites W2053236886 @default.
- W2024253043 cites W2074013990 @default.
- W2024253043 cites W2078160716 @default.
- W2024253043 cites W2078713449 @default.
- W2024253043 cites W2079434139 @default.
- W2024253043 cites W2084580260 @default.
- W2024253043 cites W2088671665 @default.
- W2024253043 cites W2089216507 @default.
- W2024253043 cites W2094879921 @default.
- W2024253043 cites W2098782795 @default.
- W2024253043 cites W2102656055 @default.
- W2024253043 cites W2103203428 @default.
- W2024253043 cites W2103681330 @default.
- W2024253043 cites W2105510993 @default.
- W2024253043 cites W2105615403 @default.
- W2024253043 cites W2106386934 @default.
- W2024253043 cites W2129213133 @default.
- W2024253043 cites W2142474444 @default.
- W2024253043 cites W2145084045 @default.
- W2024253043 cites W2147304506 @default.
- W2024253043 cites W2154263643 @default.
- W2024253043 cites W2154369914 @default.
- W2024253043 cites W2163163793 @default.
- W2024253043 cites W2163673354 @default.
- W2024253043 cites W2164316626 @default.
- W2024253043 cites W2321691397 @default.
- W2024253043 cites W2949835739 @default.
- W2024253043 cites W2951114800 @default.
- W2024253043 cites W2951521406 @default.
- W2024253043 cites W2951737303 @default.
- W2024253043 doi "https://doi.org/10.1016/j.jorganchem.2011.06.031" @default.
- W2024253043 hasPublicationYear "2011" @default.
- W2024253043 type Work @default.
- W2024253043 sameAs 2024253043 @default.
- W2024253043 citedByCount "29" @default.
- W2024253043 countsByYear W20242530432012 @default.
- W2024253043 countsByYear W20242530432013 @default.
- W2024253043 countsByYear W20242530432014 @default.
- W2024253043 countsByYear W20242530432015 @default.
- W2024253043 countsByYear W20242530432016 @default.
- W2024253043 countsByYear W20242530432018 @default.
- W2024253043 countsByYear W20242530432019 @default.
- W2024253043 countsByYear W20242530432020 @default.
- W2024253043 countsByYear W20242530432021 @default.
- W2024253043 countsByYear W20242530432023 @default.