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- W2024256434 abstract "Tripivaloylmethane [systematic name: 4-(2,2-dimethylpropanoyl)-2,2,6,6-tetramethylheptane-3,5-dione], C16H28O3, is a 1,3,3′-triketone with C3 molecular symmetry, prepared by α-acylation of 2,2,6,6-tetramethylheptane-3,5-dione with 2,2-dimethylpropanoyl anhydride in the presence of barium metal. The molecules are conformationally chiral and pack so that each molecular site is occupied with equal probability by the two enantiomers. The carbonyl groups of the two superimposed enantiomeric molecules are at an angle of 75.4 (16)°." @default.
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- W2024256434 date "2007-05-11" @default.
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- W2024256434 title "Conformational enantiomeric disorder in tripivaloylmethane" @default.
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- W2024256434 doi "https://doi.org/10.1107/s0108270107012474" @default.
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