Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024256524> ?p ?o ?g. }
Showing items 1 to 59 of
59
with 100 items per page.
- W2024256524 endingPage "221" @default.
- W2024256524 startingPage "221" @default.
- W2024256524 abstract "The stereochemical course of the dehydrohalogenation of the diastereoisomeric 1-chloro- and 1-bromo-1,2-diphenyl-2-p-tolylsulphonylethanes (I)–(IV) has been studied. A broad spectrum of base–solvent pairs has been employed. For all the reagents used the erythro-isomers (I) and (III) invariably gave anti-elimination. The threo-isomers (II) and (IV) followed a course strongly dependent upon the nature of the base. In reactions promoted by anionic bases the importance of the syn-component increased with the strength of the reagents. Addition of a crown ether did not cause a significant effect. When amines were used the stereochemical outcome was influenced by the nature of the leaving group, of the solvent, and of the attacking base. The observations are briefly discussed in the light of current views concerning elimination reactions. The use of diethylaminomethylpolystyrene as a dehydrohalogenating agent has been also tested." @default.
- W2024256524 created "2016-06-24" @default.
- W2024256524 creator A5001606841 @default.
- W2024256524 creator A5006813955 @default.
- W2024256524 creator A5009958236 @default.
- W2024256524 creator A5038389175 @default.
- W2024256524 date "1975-01-01" @default.
- W2024256524 modified "2023-09-26" @default.
- W2024256524 title "Dehydrohalogenation of threo- and erythro-1-chloro-and 1-bromo-1,2-diphenyl-2-p-tolylsulphonylethanes. A survey of the stereochemical course" @default.
- W2024256524 doi "https://doi.org/10.1039/p29750000221" @default.
- W2024256524 hasPublicationYear "1975" @default.
- W2024256524 type Work @default.
- W2024256524 sameAs 2024256524 @default.
- W2024256524 citedByCount "5" @default.
- W2024256524 crossrefType "journal-article" @default.
- W2024256524 hasAuthorship W2024256524A5001606841 @default.
- W2024256524 hasAuthorship W2024256524A5006813955 @default.
- W2024256524 hasAuthorship W2024256524A5009958236 @default.
- W2024256524 hasAuthorship W2024256524A5038389175 @default.
- W2024256524 hasConcept C121332964 @default.
- W2024256524 hasConcept C1276947 @default.
- W2024256524 hasConcept C138716334 @default.
- W2024256524 hasConcept C155647269 @default.
- W2024256524 hasConcept C161790260 @default.
- W2024256524 hasConcept C178790620 @default.
- W2024256524 hasConcept C185592680 @default.
- W2024256524 hasConcept C2777552389 @default.
- W2024256524 hasConcept C2779506367 @default.
- W2024256524 hasConcept C71240020 @default.
- W2024256524 hasConceptScore W2024256524C121332964 @default.
- W2024256524 hasConceptScore W2024256524C1276947 @default.
- W2024256524 hasConceptScore W2024256524C138716334 @default.
- W2024256524 hasConceptScore W2024256524C155647269 @default.
- W2024256524 hasConceptScore W2024256524C161790260 @default.
- W2024256524 hasConceptScore W2024256524C178790620 @default.
- W2024256524 hasConceptScore W2024256524C185592680 @default.
- W2024256524 hasConceptScore W2024256524C2777552389 @default.
- W2024256524 hasConceptScore W2024256524C2779506367 @default.
- W2024256524 hasConceptScore W2024256524C71240020 @default.
- W2024256524 hasIssue "3" @default.
- W2024256524 hasLocation W20242565241 @default.
- W2024256524 hasOpenAccess W2024256524 @default.
- W2024256524 hasPrimaryLocation W20242565241 @default.
- W2024256524 hasRelatedWork W2004632246 @default.
- W2024256524 hasRelatedWork W2019571757 @default.
- W2024256524 hasRelatedWork W2042277837 @default.
- W2024256524 hasRelatedWork W2117726062 @default.
- W2024256524 hasRelatedWork W2313903746 @default.
- W2024256524 hasRelatedWork W2319975488 @default.
- W2024256524 hasRelatedWork W2395516437 @default.
- W2024256524 hasRelatedWork W2400736630 @default.
- W2024256524 hasRelatedWork W2952827678 @default.
- W2024256524 hasRelatedWork W3119131008 @default.
- W2024256524 isParatext "false" @default.
- W2024256524 isRetracted "false" @default.
- W2024256524 magId "2024256524" @default.
- W2024256524 workType "article" @default.