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• W2024265736 endingPage "373" @default.
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• W2024265736 abstract "The reactions between two polyisocyanates, 4,4′-methylenebis(phenyl isocyanate) (MDI) and trimer of isophorone diisocyanate (tIPDI) and a model aryl–alkyl diurethane were carried out at high temperature (≥170 °C) and several NCO/urethane ratios. A combination of 1H and 13C NMR and MALDI-TOF spectroscopies was used and allows the identification of reaction products. When MDI or tIPDI is reacted with a diurethane at high temperature and after cooled, allophanates are formed but not isocyanurates. 13C NMR was used to quantify the different reaction products obtained under different experimental conditions. Only a few allophanates (≤10%) are obtained after 1 h of reaction." @default.
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• W2024265736 date "2005-11-01" @default.
• W2024265736 modified "2023-10-13" @default.
• W2024265736 title "Reactivity of isocyanates with urethanes: Conditions for allophanate formation" @default.
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• W2024265736 doi "https://doi.org/10.1016/j.polymdegradstab.2005.01.045" @default.
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