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- W2024266209 abstract "Abstract A calculation using the DFT method confirmed that the extraordinary stability of the triazenes formed by an azo coupling reaction of 5‐nitrobenzo[ c ]‐1,2‐thiazole‐3‐diazonium with primary or secondary aromatic amines is caused by the fact that these substances are protonated at the heterocyclic nitrogen atom and not at the nitrogen atom of the triazene grouping –N=N–N(R)Ar. Stable triazenes are also formed by reaction of 5‐nitrobenzo[ c ]‐1,2‐thiazole‐3‐diazonium with 2‐alkylaminonaphthalenes. In the cases of the azo coupling reaction with 2‐methylamino‐ and 2‐ethylaminonaphthalene, the content of triazenes is almost 50 % in the product mixture with the isomeric azo compounds. The structures of the triazenes were confirmed by X‐ray analysis.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)" @default.
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- W2024266209 date "2008-06-17" @default.
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- W2024266209 title "Stable Triazenes Derived from 2‐Alkylaminonaphthalenes and 5‐Nitrobenzo[<i>c</i>]‐1,2‐thiazole‐3‐diazonium Hydrogensulfate" @default.
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