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• W2024267235 abstract "A series of bis(2-(3,4-ethylenedioxy)thiophene)-based monomers have been synthesized and fully characterized; specifically (E)-1,2-bis(2-(3,4-ethylenedioxy)thienyl)vinylene (BEDOT-V), 1,4-bis(2-(3,4-ethylenedioxy)thienyl)benzene (BEDOT-B), 4,4‘-bis(2-(3,4-ethylenedioxy)thienyl)biphenyl (BEDOT-BP), 2,5-bis(2-(3,4-ethylenedioxy)thienyl)furan (BEDOT-F), 2,5-bis(2-(3,4-ethylenedioxy)thienyl)-thiophene (BEDOT-T), and 2,2‘:5‘,2‘‘-ter(3,4-ethylenedioxy)thiophene, TER-EDOT. The X-ray crystal structures of BEDOT-V and BEDOT-B have been determined. These monomers oxidize and polymerize at low potentials relative to other reported electropolymerizable heterocycles. The electroactive polymers formed exhibit low redox switching potentials and are quite stable in the conducting state. TER-EDOT was found to have the lowest peak oxidation potential of +0.2 V vs Ag/Ag+, making it the most easily oxidized polymerizable thiophene monomer reported. The electronic bandgaps of these EDOT based polymers range from 1.4 to 2.3 eV..." @default.
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• W2024267235 date "1996-01-01" @default.
• W2024267235 modified "2023-10-18" @default.
• W2024267235 title "Electrochromic Conducting Polymers via Electrochemical Polymerization of Bis(2-(3,4-ethylenedioxy)thienyl) Monomers" @default.
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• W2024267235 doi "https://doi.org/10.1021/cm9504798" @default.
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