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• W2024268906 abstract "Electrical conductivities of Gd-doped (0.15 mol %) and nominally pure nanocrystalline ceramics (∼30 nm grain size) were measured by impedance spectroscopy in the temperature range of 673-773 K under various oxygen partial pressures (1- Pa). The ionic and electronic contributions were separated using electrochemical polarization with an electronically blocking electrode, yttria-stabilized zirconia. The results allow for a clear distinction between potential explanations. It is shown that the space charge model (space charge zones with potential of ∼0.3 V resulting in depletion of oxygen vacancies and accumulation of conduction electrons) explains all the experimental features. © 2002 The Electrochemical Society. All rights reserved." @default.
• W2024268906 created "2016-06-24" @default.
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• W2024268906 date "2002-01-01" @default.
• W2024268906 modified "2023-10-07" @default.
• W2024268906 title "On the Conductivity Mechanism of Nanocrystalline Ceria" @default.
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• W2024268906 doi "https://doi.org/10.1149/1.1507597" @default.
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