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- W2024269666 abstract "Six new beta-amino acid-containing cyclic depsipeptides, termed ulongamides A-F (1-6), have been isolated from collections of apratoxin-producing cyanobacteria from Palau. Their planar structures have been determined by NMR spectroscopic techniques. The absolute stereochemistry of the hydroxy acid and all the alpha-amino acid-derived units was ascertained to be S by chiral HPLC analysis of degradation products. The stereochemistry of the beta-amino acid moiety, 3-amino-2-methylhexanoic acid, was established by advanced Marfey analysis of the acid hydrolyzates and found to be 2R,3R in compounds 1-3 but 2S,3R in compounds 4-6. All compounds except 6, which lacks an aromatic amino acid moiety, were weakly cytotoxic against KB cells." @default.
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- W2024269666 date "2002-06-25" @default.
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- W2024269666 title "Ulongamides A−F, New β-Amino Acid-Containing Cyclodepsipeptides from Palauan Collections of the Marine Cyanobacterium <i>Lyngbya</i> sp." @default.
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- W2024269666 doi "https://doi.org/10.1021/np0200461" @default.
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