FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024274998> ?p ?o ?g. }

• W2024274998 endingPage "44" @default.
• W2024274998 startingPage "38" @default.
• W2024274998 abstract "Abstract CAE surfactants ( c arboxylic a cid e nd-standing triblock copolymers of poly(ethylene oxide)–poly(propylene oxide)–poly(ethylene oxide)) are amphiphiles that are able to bind multivalent cations thermoreversibly; a property that can be used to develop new environmentally friendly separation and ion exchange applications. The analysis of the binding of multivalent ions to CAE micelles is more difficult as compared to conventional surfactants because of its thermo-responsive micellization behavior and its low CMC at room temperature. Conventional analysis techniques like conductometry and surface tensiometry are highly sensitive to temperature and are therefore very difficult to apply in surfactant solutions with strong temperature dependent micellization behavior. For this reason, binding of multivalent ions to CAE micelles has been investigated using isothermal titration calorimetry (ITC) and an alternative conductometric analysis method. Conductometry was used to construct ‘Eisenberg’ plots, which show the binding and release behavior of monovalent ions in the presence of multivalent ions. Regarding the CAE-85 (modified Pluronic P85) micellar system, both methods provide information about the exchange of multivalent cations for monovalent ions above the critical micellization temperature (CMT) of CAE-85. ITC results confirm that dehydration of multivalent ions plays a dominant role in the observed heat effect during the titration of multivalent chloride salts to CAE-85 solutions. The multivalent ions investigated in this study are Ca 2+ , Cu 2+ , Zn 2+ , Co 2+ , Mg 2+ , Ba 2+ , Mn 2+ and La 3+ . Additionally, using the alternative conductivity approach a change in micellar shape was observed upon the addition of multivalent ions when the molar amount of cationic charges balances the molar amount of anionic carboxylate end groups of the surfactant." @default.
• W2024274998 created "2016-06-24" @default.
• W2024274998 creator A5001576457 @default.
• W2024274998 creator A5032679645 @default.
• W2024274998 creator A5070371742 @default.
• W2024274998 creator A5076348191 @default.
• W2024274998 date "2010-05-01" @default.
• W2024274998 modified "2023-09-27" @default.
• W2024274998 title "Characterization of the binding of multivalent ions to modified pluronic micelles by isothermal titration calorimetry and modified conductometry" @default.
• W2024274998 cites W1963561585 @default.
• W2024274998 cites W1971128501 @default.
• W2024274998 cites W1973207347 @default.
• W2024274998 cites W1976554038 @default.
• W2024274998 cites W1979181446 @default.
• W2024274998 cites W1981309497 @default.
• W2024274998 cites W1982601865 @default.
• W2024274998 cites W2003458405 @default.
• W2024274998 cites W2003530551 @default.
• W2024274998 cites W2007909018 @default.
• W2024274998 cites W2008571237 @default.
• W2024274998 cites W2011775908 @default.
• W2024274998 cites W2011930569 @default.
• W2024274998 cites W2018880591 @default.
• W2024274998 cites W2026795127 @default.
• W2024274998 cites W2028364073 @default.
• W2024274998 cites W2028394360 @default.
• W2024274998 cites W2042976956 @default.
• W2024274998 cites W2046713036 @default.
• W2024274998 cites W2048023777 @default.
• W2024274998 cites W2050224719 @default.
• W2024274998 cites W2070101046 @default.
• W2024274998 cites W2074376860 @default.
• W2024274998 cites W2077859007 @default.
• W2024274998 cites W2081906578 @default.
• W2024274998 cites W2086176838 @default.
• W2024274998 cites W2087967597 @default.
• W2024274998 cites W2094308540 @default.
• W2024274998 cites W2121403884 @default.
• W2024274998 cites W2158844256 @default.
• W2024274998 cites W2162467336 @default.
• W2024274998 cites W2166555853 @default.
• W2024274998 doi "https://doi.org/10.1016/j.colsurfa.2010.03.010" @default.
• W2024274998 hasPublicationYear "2010" @default.
• W2024274998 type Work @default.
• W2024274998 sameAs 2024274998 @default.
• W2024274998 citedByCount "7" @default.
• W2024274998 countsByYear W20242749982012 @default.
• W2024274998 countsByYear W20242749982013 @default.
• W2024274998 countsByYear W20242749982014 @default.
• W2024274998 countsByYear W20242749982019 @default.
• W2024274998 countsByYear W20242749982020 @default.
• W2024274998 crossrefType "journal-article" @default.
• W2024274998 hasAuthorship W2024274998A5001576457 @default.
• W2024274998 hasAuthorship W2024274998A5032679645 @default.
• W2024274998 hasAuthorship W2024274998A5070371742 @default.
• W2024274998 hasAuthorship W2024274998A5076348191 @default.
• W2024274998 hasConcept C101335993 @default.
• W2024274998 hasConcept C11268172 @default.
• W2024274998 hasConcept C121332964 @default.
• W2024274998 hasConcept C133347239 @default.
• W2024274998 hasConcept C147789679 @default.
• W2024274998 hasConcept C156911925 @default.
• W2024274998 hasConcept C15920480 @default.
• W2024274998 hasConcept C171250308 @default.
• W2024274998 hasConcept C178790620 @default.
• W2024274998 hasConcept C179104552 @default.
• W2024274998 hasConcept C184651966 @default.
• W2024274998 hasConcept C184866935 @default.
• W2024274998 hasConcept C185592680 @default.
• W2024274998 hasConcept C192562407 @default.
• W2024274998 hasConcept C202270520 @default.
• W2024274998 hasConcept C2780841128 @default.
• W2024274998 hasConcept C43617362 @default.
• W2024274998 hasConcept C521977710 @default.
• W2024274998 hasConcept C70468152 @default.
• W2024274998 hasConcept C97355855 @default.
• W2024274998 hasConceptScore W2024274998C101335993 @default.
• W2024274998 hasConceptScore W2024274998C11268172 @default.
• W2024274998 hasConceptScore W2024274998C121332964 @default.
• W2024274998 hasConceptScore W2024274998C133347239 @default.
• W2024274998 hasConceptScore W2024274998C147789679 @default.
• W2024274998 hasConceptScore W2024274998C156911925 @default.
• W2024274998 hasConceptScore W2024274998C15920480 @default.
• W2024274998 hasConceptScore W2024274998C171250308 @default.
• W2024274998 hasConceptScore W2024274998C178790620 @default.
• W2024274998 hasConceptScore W2024274998C179104552 @default.
• W2024274998 hasConceptScore W2024274998C184651966 @default.
• W2024274998 hasConceptScore W2024274998C184866935 @default.
• W2024274998 hasConceptScore W2024274998C185592680 @default.
• W2024274998 hasConceptScore W2024274998C192562407 @default.
• W2024274998 hasConceptScore W2024274998C202270520 @default.
• W2024274998 hasConceptScore W2024274998C2780841128 @default.
• W2024274998 hasConceptScore W2024274998C43617362 @default.
• W2024274998 hasConceptScore W2024274998C521977710 @default.
• W2024274998 hasConceptScore W2024274998C70468152 @default.
• W2024274998 hasConceptScore W2024274998C97355855 @default.
• W2024274998 hasIssue "1-3" @default.
• W2024274998 hasLocation W20242749981 @default.

• next