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- W2024279074 abstract "Olivine LiFePO 4 particles were prepared by solid-state reaction using Li 2 CO 3 , (NH 4 ) 2 HPO 4 and FeC 2 O 4 2H 2 O as raw materials, and they were coated with an appropriate amount of carbon through thermal decomposition of C 16 H 10 pyrene. Cathodes using the olivine particles were subjected to an open-circuit voltage measurement under the relaxation condition of 24 h at each SOC and DOD states. The electrochemical reaction in the LiFePO 4 cathode was composed of a large plateau around 3.45 V with sloped regions nearby for both the fully charged and discharged states. It was found that the sloped region widths exhibited a hysteresis, that is, they depend on the direction of the redox reaction. Furthermore, both sloped regions became narrower when the operating temperature was raised from 30 °C to 60 °C. These facts implied that the obtained profiles were not in an equilibrium state with a quasi-OCV profile than the real one, and that the potential relaxation in the sloped regions took an extremely long time (more than 24 h)." @default.
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- W2024279074 date "2010-10-01" @default.
- W2024279074 modified "2023-10-16" @default.
- W2024279074 title "Open-circuit voltage study on LiFePO4 olivine cathode" @default.
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- W2024279074 doi "https://doi.org/10.1016/j.jpowsour.2010.04.072" @default.
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