Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024281282> ?p ?o ?g. }
- W2024281282 endingPage "438" @default.
- W2024281282 startingPage "434" @default.
- W2024281282 abstract "Abstract We have investigated the hydrogen storage properties of the LiAlH4–LiBH4 system, both un-doped and doped with titanium based catalysts. It was found that TiF3 exhibited the superior catalytic effects in terms of enhancing the hydriding/dehydriding kinetics and reducing the dehydrogenation temperature of the LiAlH4–LiBH4 system. Compared to the un-doped LiAlH4–LiBH4 system, the onset temperatures of the 5 mol% TiF3-doped sample for the first and second dehydrogenation steps were decreased by 64 and 150 °C, respectively. X-ray diffraction patterns of the dehydrogenated samples revealed that the produced Al from LiAlH4 could react with B from the decomposition of LiBH4 to form AlB2 and LiAl compounds. Pressure-composition-temperature (PCT) and van’t Hoff plots made it clear that the decomposition enthalpy of LiBH4 in the TiF3-doped LiAlH4–LiBH4 system is decreased from 74 kJ/(mol of H2) for the pure LiBH4 to 60.4 kJ/(mol of H2). The dehydrogenation products of the TiF3-doped LiAlH4–LiBH4 sample can absorb 3.76 and 4.78 wt.% of hydrogen in 1 h and 14 h, respectively, at 600 °C and under 4 MPa of hydrogen. The formation of LiBH4 was detected by X-ray diffraction in the rehydrogenated sample." @default.
- W2024281282 created "2016-06-24" @default.
- W2024281282 creator A5010772578 @default.
- W2024281282 creator A5013881064 @default.
- W2024281282 creator A5023330003 @default.
- W2024281282 creator A5060974161 @default.
- W2024281282 date "2009-11-01" @default.
- W2024281282 modified "2023-09-24" @default.
- W2024281282 title "Reversible hydrogen storage in titanium-catalyzed LiAlH4–LiBH4 system" @default.
- W2024281282 cites W1570196808 @default.
- W2024281282 cites W1576689615 @default.
- W2024281282 cites W1976986947 @default.
- W2024281282 cites W1979161708 @default.
- W2024281282 cites W1995971836 @default.
- W2024281282 cites W2000304254 @default.
- W2024281282 cites W2000791207 @default.
- W2024281282 cites W2002765673 @default.
- W2024281282 cites W2005302882 @default.
- W2024281282 cites W2006138445 @default.
- W2024281282 cites W2008583144 @default.
- W2024281282 cites W2028326848 @default.
- W2024281282 cites W2030288349 @default.
- W2024281282 cites W2031106109 @default.
- W2024281282 cites W2035639699 @default.
- W2024281282 cites W2039990290 @default.
- W2024281282 cites W2041093472 @default.
- W2024281282 cites W2042757057 @default.
- W2024281282 cites W2043192670 @default.
- W2024281282 cites W2044552255 @default.
- W2024281282 cites W2046120957 @default.
- W2024281282 cites W2071038343 @default.
- W2024281282 cites W2071321945 @default.
- W2024281282 cites W2076942610 @default.
- W2024281282 cites W2085084854 @default.
- W2024281282 cites W2100508707 @default.
- W2024281282 cites W2102097343 @default.
- W2024281282 cites W2115842025 @default.
- W2024281282 cites W2120192352 @default.
- W2024281282 cites W2120901659 @default.
- W2024281282 cites W2121120269 @default.
- W2024281282 cites W2125801497 @default.
- W2024281282 cites W2143294757 @default.
- W2024281282 cites W2161873423 @default.
- W2024281282 cites W2167383445 @default.
- W2024281282 cites W2323306385 @default.
- W2024281282 cites W2949680281 @default.
- W2024281282 cites W2951170252 @default.
- W2024281282 cites W3186783296 @default.
- W2024281282 cites W89651134 @default.
- W2024281282 doi "https://doi.org/10.1016/j.jallcom.2009.07.158" @default.
- W2024281282 hasPublicationYear "2009" @default.
- W2024281282 type Work @default.
- W2024281282 sameAs 2024281282 @default.
- W2024281282 citedByCount "50" @default.
- W2024281282 countsByYear W20242812822012 @default.
- W2024281282 countsByYear W20242812822013 @default.
- W2024281282 countsByYear W20242812822014 @default.
- W2024281282 countsByYear W20242812822015 @default.
- W2024281282 countsByYear W20242812822016 @default.
- W2024281282 countsByYear W20242812822017 @default.
- W2024281282 countsByYear W20242812822018 @default.
- W2024281282 countsByYear W20242812822019 @default.
- W2024281282 countsByYear W20242812822020 @default.
- W2024281282 countsByYear W20242812822021 @default.
- W2024281282 countsByYear W20242812822022 @default.
- W2024281282 crossrefType "journal-article" @default.
- W2024281282 hasAuthorship W2024281282A5010772578 @default.
- W2024281282 hasAuthorship W2024281282A5013881064 @default.
- W2024281282 hasAuthorship W2024281282A5023330003 @default.
- W2024281282 hasAuthorship W2024281282A5060974161 @default.
- W2024281282 hasConcept C127413603 @default.
- W2024281282 hasConcept C161790260 @default.
- W2024281282 hasConcept C178790620 @default.
- W2024281282 hasConcept C185592680 @default.
- W2024281282 hasConcept C191897082 @default.
- W2024281282 hasConcept C192562407 @default.
- W2024281282 hasConcept C42360764 @default.
- W2024281282 hasConcept C506065880 @default.
- W2024281282 hasConcept C512968161 @default.
- W2024281282 hasConcept C68044625 @default.
- W2024281282 hasConceptScore W2024281282C127413603 @default.
- W2024281282 hasConceptScore W2024281282C161790260 @default.
- W2024281282 hasConceptScore W2024281282C178790620 @default.
- W2024281282 hasConceptScore W2024281282C185592680 @default.
- W2024281282 hasConceptScore W2024281282C191897082 @default.
- W2024281282 hasConceptScore W2024281282C192562407 @default.
- W2024281282 hasConceptScore W2024281282C42360764 @default.
- W2024281282 hasConceptScore W2024281282C506065880 @default.
- W2024281282 hasConceptScore W2024281282C512968161 @default.
- W2024281282 hasConceptScore W2024281282C68044625 @default.
- W2024281282 hasIssue "1-2" @default.
- W2024281282 hasLocation W20242812821 @default.
- W2024281282 hasOpenAccess W2024281282 @default.
- W2024281282 hasPrimaryLocation W20242812821 @default.
- W2024281282 hasRelatedWork W2022507789 @default.
- W2024281282 hasRelatedWork W2048736733 @default.
- W2024281282 hasRelatedWork W2320186725 @default.
- W2024281282 hasRelatedWork W2748952813 @default.