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- W2024291275 abstract "Abstract The formation of adduct-complexes has been studied, between tris(thenoyltrifluoroacetonato)europium(III) (Eu A 3 ) and tributyl phosphate (TBP), by an extraction method. Two types of adducts Eu A 3 · S and Eu A 3 ·2 S (where S is TBP) have been found in the present system. Stabilities of these adducts have been determined by a method of curve-fitting in twelve inert solvents. Changes of the equilibrium constants in different solvents have been explained in connection with the activity coefficients, which can be calculated on the basis of the solubility parameter concept; the first and second adduct formation constants in terms of activities have been evaluated at log k 1 0 = 4·39 and log k 2 0 = 2·98, respectively. A correlation between the stabilities of the two adducts has also been explained with respect to solvent changes. It has been found that the formation constant of Eu A 3 · S changes in proportion to that of Sc A 3 · S ." @default.
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- W2024291275 date "1973-07-01" @default.
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- W2024291275 title "Some regularities in the formation constants of TBP adducts of europium tris-TTA chelate" @default.
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- W2024291275 doi "https://doi.org/10.1016/0022-1902(73)80320-3" @default.
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