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- W2024296847 abstract "The development of practical approaches for the construction of carbon–sulfur bonds is of interest to scientists. In particular, carbon–sulfur bond formation by transition-metal-catalyzed allylations has been attracting great attention. Allylic sulfides are important substances owing to their broad applications in synthetic and pharmaceutical areas. The alkene and sulfur moieties in allylic sulfides can lead to numerous transformations. This review details the development of carbon–sulfur bond formation through palladium-catalyzed rearrangements, palladium-catalyzed allylations, iridium-catalyzed regio- and enantioselective allylations and miscellaneous metal-catalyzed allylic substitutions. Carbon–selenium bond formations via metal-catalyzed allylic substitutions are also reviewed. 1Introduction 2Carbon–Sulfur Bond Formation via Palladium-Catalyzed Reactions 2.1Rearrangements of Allylic Substrates 2.2Allylations 2.3Asymmetric Allylations 3Carbon–Sulfur Bond Formation via Iridium-Catalyzed Regio- and Enantioselective Allylations 4Carbon–Sulfur Bond Formation via Miscellaneous Metal-Catalyzed Reactions 4.1Nickel 4.2Ruthenium 4.3Gallium 4.4Iron 5Carbon–Selenium Bond Formation via Metal-Catalyzed Allylic Substitutions 6Conclusions" @default.
- W2024296847 created "2016-06-24" @default.
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- W2024296847 date "2013-10-01" @default.
- W2024296847 modified "2023-09-24" @default.
- W2024296847 title "ChemInform Abstract: Carbon-Sulfur Bond Formation via Metal-Catalyzed Allylations of Sulfur Nucleophiles" @default.
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- W2024296847 doi "https://doi.org/10.1002/chin.201342234" @default.
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