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- W2024298041 abstract "Acylated C-glycopyranosyl thioformamides of d-gluco, d-galacto, and d-xylo configuration were obtained by treating the corresponding glycosyl cyanides with hydrogen sulfide in the presence of triethylamine. The thioformamides gave 3,5-bis-(β-d-glycopyranosyl)-1,2,4-thiadiazoles in reactions with potassium bromate and sodium dithionite in dichloromethane–water biphasic solvent mixture. Deprotected derivatives were prepared by Zemplén deacylation." @default.
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- W2024298041 date "2001-06-01" @default.
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- W2024298041 title "Preparation of 3,5-bis-(β- d -glycopyranosyl)-1,2,4-thiadiazoles from C -(β- d -glycopyranosyl)thioformamides" @default.
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- W2024298041 doi "https://doi.org/10.1016/s0040-4020(01)00444-6" @default.
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