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- W2024302247 abstract "A carbohydrate-based oxepine, derived from 2-deoxy-D-arabino-hexopyranose, was used to prepare a family of septanosyl-1,2,3-triazoles in four steps. DMDO mediated epoxidation of the oxepine followed by trapping of the intermediate 1,2-anhydroseptanose by sodium azide gave the beta-substituted glycosyl azide. The septanosyl azide was then reacted with a number of alkynes under thermal Huisgen or copper(I) mediated reaction conditions. Hydrogenolysis of benzyl protecting groups gave substituted septanosyl-1,2,3-triazoles. The new septanose-based structures were then evaluated as potential glycosidase inhibitors." @default.
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- W2024302247 date "2007-07-01" @default.
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- W2024302247 title "Synthesis of substituted septanosyl-1,2,3-triazoles" @default.
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- W2024302247 doi "https://doi.org/10.1016/j.carres.2007.03.026" @default.
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