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- W2024306779 abstract "Abstract The molecular and crystal structure of the synthetic, terminally blocked, model dipeptide t -Boc-L-Val- Δ Ala-OMe ( 1 ) was determined by single-crystal X-ray diffraction. Crystal data for 1 are: C 14 H 24 N 2 O 5 , hexagonal, space group P 6 5 (no. 170), a = 10.800(2) Å, c = 27.077(2) Å, and Z = 6. The crystal structure was solved by direct methods. The least-squares refinement led to R and R w values of 0.077 and 0.075, respectively, for 1298 reflections with F ≥ 5 σ ( F ). The conformation of the Val residue is partially extended, while that of the Δ Ala residue is trans , cis . The N-terminal protecting group is in the trans , trans disposition." @default.
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- W2024306779 date "1993-01-01" @default.
- W2024306779 modified "2023-09-27" @default.
- W2024306779 title "Molecular and crystal structure of a dehydroalanine dipeptide*" @default.
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- W2024306779 doi "https://doi.org/10.1524/zkri.1993.207.part-1.25" @default.
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