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- W2024320050 abstract "Six 1,3,5-trisubstituted 1,4-diazepin-2-ones were synthesized by a sequence featuring the cascade addition of vinyl Grignard to N-[Boc-aminoacyl]-N-alkyl-beta-amino esters, followed by Boc group removal and annulation by a reductive amination. Relative to the parent sequence employing N-Boc-aminoacyl beta-amino esters to make 3,5-disubstituted heterocycle, the additional N-alkyl substituent caused a noticeable acceleration and gave relatively higher yield in the 1,4-diazepin-2-one annulation." @default.
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- W2024320050 date "2007-10-10" @default.
- W2024320050 modified "2023-10-03" @default.
- W2024320050 title "1,3,5-Trisubstituted 1,4-Diazepin-2-ones" @default.
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- W2024320050 doi "https://doi.org/10.1021/jo701467d" @default.
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