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• W2024321124 abstract "Abstract A kinetic study of Hg 2+ catalyzed solvolysis of linkage isomers [Pd(AAA)XCN/NCX] + (AAA = 1,1,7,7-tetraethyldiethylenetriamine (Et 4 dien) and 4-methyl-1,1,7,7-tetraethydiethylenetriamine (MeEt 4 dien); X = S, Se) has been carried out in methanol at 25 °C. The kinetic results show that the catalytic efficiency of mercury(II) in removing the thiocyanate or selenocyanate ligands is greater in the PdXCN substrates than in the PdNCX ones, depending on whether the sulfur or selenium atom on which the attack by Hg 2+ takes place, is bonded directly to palladium(II). The kinetic data for the isomerization and substitution reactions are also reported." @default.
• W2024321124 created "2016-06-24" @default.
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• W2024321124 date "1978-01-01" @default.
• W2024321124 modified "2023-09-27" @default.
• W2024321124 title "Catalyzed substitutions on cationic palladium(II) complexes. III. Mercury(II) catalyzed displacement of coordinated thiocyanate and selenocyanate linkage isomers" @default.
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• W2024321124 doi "https://doi.org/10.1016/s0020-1693(00)89011-8" @default.
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