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- W2024322585 abstract "Reactions between FeIII, dppm, CO as appropriate and LiAlH4 produce the FeII complexes trans-[Fe(Cl)(CO)(η2-dppm)2] [FeCl4]. (1a) trans-[Fe(H)2(η2-dppm)2] (2) and trans-[Fe(H)(Cl)(η2-dppm)2] (3), depending upon the reaction conditions. The trans octahedral structures, with chelating dppm ligands, of 1a and 2 have been established by X-ray crystallography. Compound 2 reacts with CO to produce the Fe0 complex Fe(CO)3(η1-dppm)2 (4), identified by NMR spectrometry, and with H2HBF4·Et2O to give the dihydrogen complex trans-[Fe(H)(η2-H2)(η2-dppm)2]BF4 (5). The dihydrogen can be replaced with, for example, CO and CH3CN to give trans-[Fe(H)(L)(η2-dppm)2]BF4 (L = CO, 6, and L = CH3CN, 7, respectively). With CS2, insertion into the Fe—bond of 5 occurs to produce the dithioformato complex cis-[Fe(η2-S2CH)(γ2-dppm)2]BF4 (8), the structure of which is also reported." @default.
- W2024322585 created "2016-06-24" @default.
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- W2024322585 date "1997-01-01" @default.
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- W2024322585 title "Reactions of FeIII with LiAlH4 and LiBH4 in the presence of bis(diphenylphosphino)methane (dppm) and CO. The crystal and molecular structures of trans-[Fe(Cl)(CO)(η2-dppm)2] [FeCl4], trans-Fe(H)2(η2-dppm)2 and cis-[Fe(η2-S2CH(η2-dppm)2]BF4" @default.
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- W2024322585 doi "https://doi.org/10.1016/s0277-5387(97)00025-9" @default.
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