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- W2024333043 abstract "Abstract Crystals of free base phthalocyanine (H 2 pc) and its unsubstituted metal derivatives Mpc (where M=Ni, Cu, Zn, Pb, and pc=C 32 H 16 N 8 2− =phthalocyanine ligand) were examined after being exposed to NO 2 ambient gas. Scanning electron microscopy (SEM) supported by X-ray microprobe analysis (EDAX), UV–Vis and FTIR spectroscopy as well as X-ray powder diffractometry (XRD) were applied to study the crystals chemistry and surface morphology. The NO 2 molecules were found to penetrate the crystal unit which led to the breakdown of the phthalocyanine macrocycle. The surface of the doped crystals has been scaled and covered by a layer composed predominantly of phthalimide. Despite vacuum desorption, it has been proved some free NO 2 to be still adsorbed by the studied material." @default.
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- W2024333043 date "2002-04-01" @default.
- W2024333043 modified "2023-09-27" @default.
- W2024333043 title "Investigation of phthalocyanine crystals exposed to NO2 ambient gas" @default.
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- W2024333043 doi "https://doi.org/10.1016/s0277-5387(02)00832-x" @default.
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