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- W2024333118 abstract "Bulk crystallization rates, nucleation density, general morphological features, equilibrium melting point and absolute crystalline percentage of linear and star-branched nylon-6 have been studied as a function of branch-point functionality and temperature. Overall bulk crystallization rates were described in terms of the Avrami equation and crystallization half-times. No significant differences in bulk crystallization rates as a function of crystallization temperature or absolute crystalline percentage were observed between linear, three-arm and six-arm samples with identical thermal history. Equilibrium melting points obtained by Hoffman Weeks analysis were reduced in star-branched nylon-6 compared to the linear polymer of comparable molecular weight. In order to deconvolute the effects of a decreased thermodynamic driving force for formation of crystals of branched polymers, crystallization half-times were measured as a function of supercooling. The crystallization half-times of star-branched nylon-6 as a function of supercooling were reduced compared to those of linear nylon-6 of comparable molecular weight. The general spherulitic superstructure appeared unaffected by increasing branch-point functionality up to six. However, irregularities in lamellar structure were implied by SAXS experiments on samples with branch-point functionality as low as three." @default.
- W2024333118 created "2016-06-24" @default.
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- W2024333118 date "1993-01-01" @default.
- W2024333118 modified "2023-10-16" @default.
- W2024333118 title "Crystallization kinetics and morphological features of star-branched nylon-6: effect of branch-point functionality" @default.
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- W2024333118 doi "https://doi.org/10.1016/0032-3861(93)90817-t" @default.
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