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- W2024333522 abstract "The reaction of (η5-C5H5)2NbCl2 with P4S10 in an alcohol ROH affords two types of compounds: paramagnetic niobium(IV) complexes formulated as [(η5-C5H5)2Nb[S2P(OR)2]]+PF−6. The e.s.r. spectra correspond to the interaction of the unpaired electron with the 93Nb and 31P nuclei. They show a significant delocalization over the phosphorus and indicate the unpaired electron lies in the dx2−y2 orbital; diamagnetic niobium(V) complexes [(η5C5H5)2NbS2[SP(S)(OR)2]] containing a NbS2 ring, for which 1H, 13C and 31P n.m.r. data are given." @default.
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- W2024333522 date "1980-01-01" @default.
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- W2024333522 title "Niobium organometallic chemistry. Part III. Reaction of bis(cyclopentadienyl)niobium dichloride with tetraphosphorus decasulphide. E.S.R. and N.M.R. Studies of some niobium(IV) and niobium(V) O,O′-dialkyldithiophosphates" @default.
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- W2024333522 doi "https://doi.org/10.1016/s0020-1693(00)93641-7" @default.
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