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• W2024337516 endingPage "4204" @default.
• W2024337516 startingPage "4196" @default.
• W2024337516 abstract "Adsorption of different gases on graphitized thermal carbon black (GTCB) has been studied with a new molecular model to examine the consequences of micropore crevices and functional groups at the junctions between adjacent basal planes. Adsorption was simulated in the Grand Canonical Monte Carlo ensemble and the theoretical Henry constants were calculated by Monte Carlo volume integration over the Boltzmann factor of the solid–fluid potential. The simulation results are in good agreement with high-resolution experimental isotherms for argon on mineralogical graphite measured by Lopez-Gonzalez et al.1 From detailed inspection of the argon isotherms at extremely low coverages, we find two distinct Henry law regions, separated by a plateau (suggesting saturation of the stronger sites) that spans over a few decades of pressure. The first Henry law region is attributed to adsorption in the ultrafine crevices at the junctions between two adjacent basal planes, and the second region corresponds to adsorption on the basal plane, as confirmed by the theoretical Henry constant. The simulated isosteric heat and snapshots of molecular configurations show that argon adsorbs preferentially in the ultrafine crevices where there is a deep potential well due to overlap from the opposite pore walls. Similar behavior was found for other nonassociating fluids (Ar, N2, and CO2); however, for associating fluids (NH3 and H2O), the strong sites for adsorption and nucleation come from the combined effects of functional groups and ultrafine crevices, since the latter cannot alone account for the observed adsorption." @default.
• W2024337516 created "2016-06-24" @default.
• W2024337516 creator A5036882860 @default.
• W2024337516 creator A5061767667 @default.
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• W2024337516 date "2015-04-01" @default.
• W2024337516 modified "2023-09-27" @default.
• W2024337516 title "Existence of Ultrafine Crevices and Functional Groups along the Edge Surfaces of Graphitized Thermal Carbon Black" @default.
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• W2024337516 doi "https://doi.org/10.1021/acs.langmuir.5b00667" @default.
• W2024337516 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25797845" @default.
• W2024337516 hasPublicationYear "2015" @default.
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