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• W2024337585 abstract "A novel rhenium phosphonio methylidyne complex [(tBuN)2Re(C-PPh3)(S-tBu)] (3) was obtained via one-pot transylidation reaction of Re(NtBu)2Cl3 (1) with [Ph3P-CH3][S-tBu] (2) and 3 equiv of phosphorus ylide Ph3PCH2. The η2-ketene rhenium(VII) complex [Re(NtBu)2{η2-(C,C)-OC−CPPh3}(S-tBu)] (4) was formed through C,C-coupling reaction of complex 3 with CO. The structure of complex 4 was confirmed with X-ray analysis." @default.
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• W2024337585 date "2005-12-17" @default.
• W2024337585 modified "2023-09-25" @default.
• W2024337585 title "Formation of η²-Ketene Rhenium(VII) Complex through the C,C-Coupling Reaction of Phosphonio Methylidyne Complexes with Carbon Monoxide" @default.
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• W2024337585 doi "https://doi.org/10.1021/om050955w" @default.
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