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- W2024342181 abstract "The polarizable point ion model for Schottky defects is extended to include the effects of induced quadrupoles in region 1. Schottky defects in AgCl are studied using this model. It is found that it is important to include induced quadrupole moments in any theoretical treatment of charged point defects in ionic crystals. Quadrupolar deformations make sizable contribution to the defect energy which ranged from −0.2 to −0.4 eV in the case of the cation vacancy over the range of anion quadrupole polarizabilities studied. The work further points to the relative significance of chlorine ions in respect of the quadrupole distortions. Das polarisierbare Punktionenmodell für Schottky-Defekte wird erweitert und schließt die Einflüsse von induzierten Quadrupolen im Bereich 1 ein. Mit diesem Modell werden Schottky-Defekte in AgCl untersucht. Es wird gefunden, daß es wesentlich ist, induzierte Quadrupolmomente in einer theoretischen Behandlung von geladenen Punktdefekten in Ionenkristallen einzubeziehen. Quadrupoldeformationen ergeben meßbare Beiträge zur Defektenergie, die von −0,2 bis −0,4 eV im Fall der Kationenleerstelle im Bereich der untersuchten Anionenquadrupolarisierbarkeiten variieren. Es wird auf die relative Bedeutung von Chlorionen für die Quadrupolverzerrungen hingewiesen." @default.
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- W2024342181 date "1991-07-01" @default.
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- W2024342181 title "An Extended Polarizable Point Ion Model for Schottky Defects" @default.
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- W2024342181 doi "https://doi.org/10.1002/pssb.2221660103" @default.
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