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- W2024346172 abstract "Abstract Chiral 1-alkoxy-3-trimethylsilyloxybuta-1,3-dienes induce a high diastereomeric excess in the cycioaddition with quinones when the chiral alkoxy group is of the type OCH(CH 3 )R with R = aryl. Also forR =vinyl. CH 2 OCH 3 the found induction is higher than that observed for R = ten. butyl. The highest diastereomeric excess (>95%) was achieved in the cycloaddifion of 1-[1-(p-methoxyphenyl)-ethoxy]-3-trimethylsilyloxybuta-1,3-diene with benzoquinone. An explanation is given based on the assumption that the R substituent is suongly enlarged in size by complexation with the used quinones." @default.
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- W2024346172 date "1990-01-01" @default.
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- W2024346172 title "Unexpectedly high diastereomeric induction in the diels-alder reaction of quinones with chiral aryl containing 1-alkoxy-3-trimethylsilyloxybuta-1,3-dienes." @default.
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- W2024346172 doi "https://doi.org/10.1016/s0040-4039(00)97288-5" @default.
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