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- W2024350061 abstract "Rotationally resolved vibrational spectra of the three lowest frequency bands of the four-membered heterocycle azetidine (c-C3H6NH) have been collected with a resolution of 0.00096 cm−1 using the far infrared beamline at the Canadian Light Source synchrotron. The modes observed correspond principally to motions best described as: β-CH2 rock (ν14) at 736.701310(7) cm−1, ring deformation (ν15) at 648.116041(8) cm−1, and the ring puckering mode (ν16) at 207.727053(9) cm−1. A global fit of 14 276 rovibrational transitions from the three bands provided an accurate set of ground state spectroscopic constants as well as excited state parameters for each of the three vibrational modes. The ground state structure was determined to be that of the puckered conformer having the NH bond in an equatorial arrangement." @default.
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- W2024350061 date "2010-12-01" @default.
- W2024350061 modified "2023-09-27" @default.
- W2024350061 title "High resolution Fourier transform infrared spectra and analysis of the ν14, ν15 and ν16 bands of azetidine" @default.
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- W2024350061 doi "https://doi.org/10.1016/j.jms.2010.09.010" @default.
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