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- W2024351994 abstract "Abstract A new transition phase has been observed in the copper complex fluoride, Tl 2 CuF 4 , with the K 2 NiF 4 -derived structure. A Rietveld refinement of the room-temperature X-ray powder pattern in the I 4/ mmm space group [ a = 4.206(2) A; c = 13.673(5) A] has confirmed the antiferrodistortive arrangement of the e g orbitals of Cu 2+ . Around 200 K a structural phase transition to a low-temperature monoclinic phase has been evidenced by DSC and X-ray diffraction [space group I 2/ m , a = 4.182(2) A, b = 4.183(2) A, c = 13.492(6) A; β = 94.564(4)°]. Tl 2 CuF 4 exhibits ferromagnetic properties below T c = 10 K. The dependence of the magnetization on the applied field is characterized at 1.7 K by a coercive field of 2.5 × 10 −2 T and a remanent magnetization of 0.6 μ B . The phase sequence has been compared with those found in La 2 CuO 4 -type compounds." @default.
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- W2024351994 date "1996-02-01" @default.
- W2024351994 modified "2023-10-18" @default.
- W2024351994 title "Structural and Magnetic Phase Transitions of the 2D Ferromagnetic Fluoride Tl2CuF4" @default.
- W2024351994 doi "https://doi.org/10.1006/jssc.1996.0086" @default.
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