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- W2024358829 abstract "Abstract The cure of B-staged Cyclotene 3022 has been studied by photoacoustic FTIR and X-ray photoelectron spectroscopy (XPS). The data indicate that the cure reaction is second-order, consistent with a Diels–Alder reaction. The lack of any loss of aromaticity on cure, as observed by both photoacoustic FTIR and XPS, and confirmed by confocal Raman spectroscopy, indicates a reaction mechanism involving the production of tetrahydronaphthalene. The lack of structural differences between surface and bulk, determined by a comparison of photoacoustic and published transmission FTIR data, indicates that the cyclobutane homopolymerization pathway lies at an energy too high to be attained even with an added surface energy. The polymer loses a significant amount of low molecular weight material on curing." @default.
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- W2024358829 date "2000-09-01" @default.
- W2024358829 modified "2023-09-27" @default.
- W2024358829 title "The surface structure of Dow Cyclotene 3022, as determined by photoacoustic FTIR, confocal Raman and photoelectron spectroscopies" @default.
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- W2024358829 doi "https://doi.org/10.1016/s0169-4332(00)00272-5" @default.
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