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- W2024370538 endingPage "557" @default.
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- W2024370538 abstract "A complex, disorder-free structure in the space group P 1 has been established for L-tryptophan, for which no crystal structure has previously been available. The 16 molecules in the asymmetric unit can be divided into two groups of eight; one where the side chains have gauche orientations and one with trans orientations. Molecules within each group have almost identical molecular geometries. The unit-cell parameters mimic a hexagonal cell, but deviations from 90° for the cell angles α = 84.421 (4) and β = 87.694 (4)° give a small tilt that rules out hexagonal symmetry. The hydrogen-bonding pattern resembles that found in the crystal structure of the racemic structure of DL-tryptophan, but a lower density combined with longer hydrogen bonds and inter-aromatic interactions show that the enantiomeric structure is less efficiently packed." @default.
- W2024370538 created "2016-06-24" @default.
- W2024370538 creator A5007594396 @default.
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- W2024370538 date "2012-09-13" @default.
- W2024370538 modified "2023-10-01" @default.
- W2024370538 title "Single-crystal investigation of <scp>L</scp>-tryptophan with <i>Z</i>′ = 16" @default.
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- W2024370538 doi "https://doi.org/10.1107/s0108768112033484" @default.
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