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- W2024372261 abstract "A detailed study of the solvent effect and of activation parameters indicates that most likely the mechanism of sulphilimine reduction by arenethiols in alcohol [1] thus: is as follows: in which the formation of 2 occurs through a cyclic transition state 3 involving the participation of one molecule of sulphilimine, one of thiol and one of alcohol. A quantitative analysis of the solvent effect through multiparametric equations evidences the relative weight of the specific and non specific solute-solvent interactions. For Ar1 = R = CH3, Ar2 = p-CH3C6H4, Ar3 = C6H5 the secondorder rate constants satisfy the following equations:" @default.
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- W2024372261 date "1980-01-01" @default.
- W2024372261 modified "2023-09-26" @default.
- W2024372261 title "The solvent effect in the reaction of N-sulphonilsulphilimines with arenethiols in alcohol" @default.
- W2024372261 doi "https://doi.org/10.1016/s0020-1693(00)92234-5" @default.
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