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- W2024373399 abstract "A differential refractometric method is used to study the temperature and composition dependence of the adsorptive properties of porous glass in 2-butoxyethanol (abbreviated C4E1)/water mixtures. The surface of the adsorbent carries hydrophobic -SiO-C8H17 as well as hydrophilic -SiOH groups. The experiments are carried out close to the liquid/liquid coexistence curve in the vicinity of the lower critical point of the system. Depending on the temperature and composition of the mixtures either C4E1 or water is preferentially adsorbed. There exists a line along which the net adsorption vanishes. For compositions x>xc (x, mole fraction of C4E1; xc, critical composition) the amount of substance of adsorbed water ñ ws(Tp) per unit gram of adsorbent at temperature Tp increases with increasing values of the temperature difference (Tp−Tc) in the range 0 K<(Tp−Tc)<4 K. Tp is the temperature of phase separation of the bulk mixture in the presence of the adsorbent. Beginning at temperatures (Tp−Tc)>4 K the adsorbed amount of substance ñ ws(Tp) decreases. At (Tp−Tc)>8 K it reaches a value which is smaller by a factor of about 10 compared with its maximum value. This phenomenon is reminiscent of a wetting transition." @default.
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- W2024373399 date "1997-01-08" @default.
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- W2024373399 title "Adsorption on hydrophobic porous glass near the liquid/liquid coexistence curve of a binary liquid mixture" @default.
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- W2024373399 doi "https://doi.org/10.1063/1.473409" @default.
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