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- W2024375262 abstract "Despite the fact that purely vibrational anharmonic resonances are diagonal in all rotational quantum numbers, it is now recognized that there may be a slight rotational dependence of the off-diagonal matrix element and that such dependence has important effects on the vibration-rotation spectrum. The effect has previously been treated empirically and numerical estimates obtained for the J-dependent terms in the Fermi resonances in a number of linear triatomic molecules. The calculation of these J-dependent terms using first-order anharmonic wavefunctions is now described and the results are compared with the experimental values in the cases of CO2 and CS2." @default.
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- W2024375262 date "1976-01-01" @default.
- W2024375262 modified "2023-09-27" @default.
- W2024375262 title "The rotational dependence of purely vibrational anharmonic resonances" @default.
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- W2024375262 doi "https://doi.org/10.1016/0584-8539(76)80205-x" @default.
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