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- W2024377421 abstract "It is known previously that bulk metallic glass compositions satisfy cluster formulae [cluster](glue atom)1,3 of 24 valence electrons as deduced from our cluster-resonance model. In the present work, it is further shown that compositions of Al-based binary and ternary quasicrystals are also explained by 24-electron cluster formulae of the types [icosahedron](glue atom)0,1, where the icosahedral cluster is identi ed from a corresponding crystalline approximant according to dense atomic packing and cluster isolation criteria, and the glue atom site is either vacant for an icosahedral quasicrystal or equal to one for a decagonal quasicrystal. Ternary quasicrystals are formulated with the same formulae as their basic binary ones but the icosahedron shell sites are substituted by third elements. The 24-electron cluster formulae are then the chemical and electronic structural units of quasicrystals, mimicking the molecular formulae of chemical substances." @default.
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- W2024377421 date "2014-08-01" @default.
- W2024377421 modified "2023-09-27" @default.
- W2024377421 title "Compositions of Al-Based Quasicrystals Interpreted by Cluster Formulae" @default.
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- W2024377421 doi "https://doi.org/10.12693/aphyspola.126.446" @default.
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