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- W2024378402 abstract "An efficient method for constructing a 10-membered carbocycle with an oxygen bridge has been developed on the basis of a formal [6+4] cycloaddition reaction. Under the influence of EtAlCl2, a dicobalt hexacarbonyl acetylene complex possessing a benzoyloxy group and an allylsilane moiety reacted with furan to give a 11-oxabicyclo[6.2.1]undec-9-ene derivative. On treatment with iodine, the cycloadduct underwent decomplexation followed by rearrangement of the oxygen bridge to afford a 11-oxabicyclo[5.3.1]undeca-1,5-diene derivative." @default.
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- W2024378402 date "2011-02-01" @default.
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- W2024378402 title "Formal [6+4] cycloaddition of a dicobalt acetylene complex with furan derivatives" @default.
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- W2024378402 doi "https://doi.org/10.1016/j.tetlet.2010.12.063" @default.
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