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- W2024381887 abstract "The kinetics of thallation of fluorene with thallium triacetate (TTA) in HOAc-H2SO4 solutions led to the rate expression The rate of thallation is found to increase with increasing acid concentration, and a sixth-order dependence on [H2SO4] is observed. Decrease in solvent polarity increases the rate of thallation. The effect of substituents is in accord with the electrophilic substitution at an aromatic system. Thallation occurs at 4-position. A mechanism similar to aromatic bromination is proposed for the thallation of fluorene." @default.
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- W2024381887 date "1978-06-01" @default.
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- W2024381887 title "Thallation of fluorenes: A kinetic and mechanistic study" @default.
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- W2024381887 doi "https://doi.org/10.1002/kin.550100605" @default.
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