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• W2024389685 endingPage "10891" @default.
• W2024389685 startingPage "10886" @default.
• W2024389685 abstract "Abstract Two polymorphs of the new cluster compound [Ru 2 Bi 14 Br 4 ](AlCl 4 ) 4 have been synthesized from Bi 24 Ru 3 Br 20 in the Lewis acidic ionic liquid [BMIM]Cl/AlCl 3 ([BMIM] + : 1‐ n ‐butyl‐3‐methylimidazolium) at 140 °C. A large fragment of the precursor’s structure, namely the [(Bi 8 )Ru(Bi 4 Br 4 )Ru(Bi 5 )] 5+ cluster, dissolved as a whole and transformed into a closely related symmetrical [(Bi 5 )Ru(Bi 4 Br 4 )Ru(Bi 5 )] 4+ cluster through structural conversion of a coordinating Bi 8 2+ to a Bi 5 + polycation, while the remainder was left intact. Both modifications have monoclinic unit cells that comprise two formula units (α form: P 2 1 / n , a =982.8(2), b =1793.2(4), c =1472.0(3) pm, β =109.05(3)°; β form: P 2 1 / n , a =1163.8(2), b =1442.7(3), c =1500.7(3), β =97.73(3)°). The [Ru 2 Bi 14 Br 4 ] 4+ cluster can be regarded as a binuclear inorganic complex of two ruthenium(I) cations that are coordinated by terminal Bi 5 + square pyramids and a central Bi 4 Br 4 ring. The presence of a covalent RuRu bond was established by molecular quantum chemical calculations utilizing real‐space bonding indicator ELI‐D. Structural similarity of the new and parent cluster suggests a structural reorganization or an exchange of the bismuth polycations as mechanisms of cluster formation. In this top‐down approach a complex‐structured unit formed at high temperature was made available for low‐temperature use." @default.
• W2024389685 created "2016-06-24" @default.
• W2024389685 creator A5027842324 @default.
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• W2024389685 date "2012-07-27" @default.
• W2024389685 modified "2023-10-18" @default.
• W2024389685 title "[Ru₂Bi₁₄Br₄](AlCl₄)₄by Mobilization and Reorganization of Complex Clusters in Ionic Liquids" @default.
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• W2024389685 doi "https://doi.org/10.1002/chem.201201038" @default.
• W2024389685 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22837108" @default.
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