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• W2024390088 endingPage "3982" @default.
• W2024390088 startingPage "3976" @default.
• W2024390088 abstract "Reported here is the preparation and property of 2D coordination networks composed of rodlike ligands with ethylene glycol side chains (1). Two 2D coordination networks, [[Co(1)2(H2O)2](NO3)2.1.5H2O]n and [[Ni(1)2(H(2)O)2](NO3)2.1.5H2O]n, have been synthesized and characterized by single-crystal X-ray diffraction, TG, DSC, UV-vis spectroscopy, and magnetic measurements. The structural analyses clarified that infinite 1D hydrogen-bond arrays composed of ethylene glycol chains contribute to the stabilization of 2D coordination frameworks, keeping the environment of substitution-active metal sites unchanged. They are more stable than a similar square-grid coordination network that does not possess an ethylene glycol chain on the ligand. We also succeeded in the direct observation of a reversible apical-ligand-exchange reaction at the cobalt(II) and nickel(II) ions in a single-crystal-to-single-crystal fashion because of the considerable stability as well as moderate flexibility of the framework. The cobalt-containing coordination network crystal showed chromic behavior depending on temperatures. Crystallographic and spectroscopic studies revealed that the color change of the crystal was attributed to the ligand-exchange process between H2O and a NO3 anion on the cobalt metal. Magnetic measurements indicated weak antiferromagnetic nearest-neighbor spin coupling between cobalt(II) ions." @default.
• W2024390088 created "2016-06-24" @default.
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• W2024390088 date "2006-04-21" @default.
• W2024390088 modified "2023-10-17" @default.
• W2024390088 title "2D Hydrogen-Bonded Square-Grid Coordination Networks with a Substitution-Active Metal Site" @default.
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• W2024390088 doi "https://doi.org/10.1021/ic052138u" @default.
• W2024390088 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16676957" @default.
• W2024390088 hasPublicationYear "2006" @default.
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