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- W2024392938 abstract "An investigation of small-angle scattering produced by polarized light from stretched and annealed polymer systems containing spherulites yields information on the supermolecular transitions that occur during such treatment. A series of semicrystalline polymer systems (films, fibers) show that stretching leads to deformation of spherulites and subsequent transformation to an orientational supermolecular order. The size of the single element C2 of the supermolecular order in the direction of stretching, determined from the distance between the layer lines of the scattering pattern, is related to the diameter D0 of the initial spherulites by the relation C2 = KD0λs, where λ, is the draw ratio of the macrosystem and K is a parameter determining the deformability of the spherulites. For polyethylene at room temperature K is unity and for polychloroprene it is 1.2. Changes of C2 after annealing and restretching of the systems also obey this ratio." @default.
- W2024392938 created "2016-06-24" @default.
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- W2024392938 date "1970-07-01" @default.
- W2024392938 modified "2023-09-24" @default.
- W2024392938 title "Relation of initial supermolecular organization in crystalline polymer systems to the organization produced by stretching" @default.
- W2024392938 doi "https://doi.org/10.1002/pol.1970.160080701" @default.
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