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- W2024395535 abstract "The chemical modification of hydroxylic group-containing cyclo- and poly-phosphazenes to introduce ethylenic and epoxide functionalities is reported. Thus, hexakis(4-hydroxyphenoxy)cyclophosphazene and poly[bis(4-hydroxyphenoxy)phosphazene] were reacted with carboxylic acids, acyl chlorides and α-bromo-methylene derivatives containing carbon-carbon double bonds, in the presence of bases or suitable condensing agents, to give unsaturated phosphazenes. These substrates were epoxidized successively under mild experimental conditions by reaction with m-chloroperbenzoic acid to produce epoxide-containing phosphazene materials. Possible practical exploitation of these new derivatives is discussed." @default.
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- W2024395535 date "1993-12-01" @default.
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- W2024395535 title "Functionalization of poly(organophosphazenes)—III. Synthesis of phosphazene materials containing carbon-carbon double bonds and epoxide groups" @default.
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- W2024395535 doi "https://doi.org/10.1016/0014-3057(93)90248-e" @default.
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