FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024402527> ?p ?o ?g. }

• W2024402527 endingPage "380" @default.
• W2024402527 startingPage "357" @default.
• W2024402527 abstract "Abstract The kinetics of chemical reactions at mineral surfaces and the rates of diffusion of species in an aqueous phase are coupled in many geochemical systems. Analytical solutions to equations describing coupled mineral dissolution/growth and solute transport in both transient and steady-state systems are used to delimit regimes of pure reaction control, pure transport control and mixed kinetic control of mass-transfer rates. The relative significance of the two processes depends on the magnitudes of the diffusion coefficients and rate constants as functions of temperature, and the degree of disequilibrium in the system. In addition, the system geometry, the ratio of mineral surface area to diffusion cross-section, and the porosity and tortuosity of the medium through which aqueous species diffuse affect reaction vs. diffusion control. In general, diffusion control increases with increasing temperature and increasing distance over which diffusion occurs. Calculations for the mixed kinetic regime in transient systems demonstrate that the relative significance of diffusion and surface reaction varies with reaction progress, and approaches a limiting value as equilibrium is approached. This limiting value may be appropriate to natural water-rock interactions that occur at conditions that are close to equilibrium. This result permits extension of simple models for irreversible mass transfer in homogeneous systems to systems in which mass-transfer kinetics are controlled by coupled surface reactions and mass transport. Criteria are established for time and length scales and fluid velocity limits on the validity of the continuum hypothesis and the local equilibrium assumption in mass-transport modeling." @default.
• W2024402527 created "2016-06-24" @default.
• W2024402527 creator A5044132845 @default.
• W2024402527 creator A5053675442 @default.
• W2024402527 creator A5059887008 @default.
• W2024402527 date "1989-12-01" @default.
• W2024402527 modified "2023-09-23" @default.
• W2024402527 title "Surface reaction versus diffusion control of mineral dissolution and growth rates in geochemical processes" @default.
• W2024402527 cites W1969392630 @default.
• W2024402527 cites W1974479088 @default.
• W2024402527 cites W1981887551 @default.
• W2024402527 cites W1992499622 @default.
• W2024402527 cites W1999165439 @default.
• W2024402527 cites W2003609307 @default.
• W2024402527 cites W2011039445 @default.
• W2024402527 cites W2019040376 @default.
• W2024402527 cites W2047694097 @default.
• W2024402527 cites W2048550424 @default.
• W2024402527 cites W2052757568 @default.
• W2024402527 cites W2055024930 @default.
• W2024402527 cites W2059467585 @default.
• W2024402527 cites W2062233268 @default.
• W2024402527 cites W2063069864 @default.
• W2024402527 cites W2064019780 @default.
• W2024402527 cites W2066527077 @default.
• W2024402527 cites W2077664513 @default.
• W2024402527 cites W2081258920 @default.
• W2024402527 cites W2085584972 @default.
• W2024402527 cites W2088673262 @default.
• W2024402527 cites W2105779189 @default.
• W2024402527 cites W2314637540 @default.
• W2024402527 cites W2314937256 @default.
• W2024402527 cites W2315892471 @default.
• W2024402527 cites W2327996905 @default.
• W2024402527 cites W2331820982 @default.
• W2024402527 cites W2335706340 @default.
• W2024402527 cites W259920609 @default.
• W2024402527 cites W88138184 @default.
• W2024402527 doi "https://doi.org/10.1016/0009-2541(89)90069-7" @default.
• W2024402527 hasPublicationYear "1989" @default.
• W2024402527 type Work @default.
• W2024402527 sameAs 2024402527 @default.
• W2024402527 citedByCount "100" @default.
• W2024402527 countsByYear W20244025272012 @default.
• W2024402527 countsByYear W20244025272013 @default.
• W2024402527 countsByYear W20244025272014 @default.
• W2024402527 countsByYear W20244025272015 @default.
• W2024402527 countsByYear W20244025272016 @default.
• W2024402527 countsByYear W20244025272017 @default.
• W2024402527 countsByYear W20244025272018 @default.
• W2024402527 countsByYear W20244025272019 @default.
• W2024402527 countsByYear W20244025272020 @default.
• W2024402527 countsByYear W20244025272021 @default.
• W2024402527 countsByYear W20244025272022 @default.
• W2024402527 crossrefType "journal-article" @default.
• W2024402527 hasAuthorship W2024402527A5044132845 @default.
• W2024402527 hasAuthorship W2024402527A5053675442 @default.
• W2024402527 hasAuthorship W2024402527A5059887008 @default.
• W2024402527 hasConcept C121332964 @default.
• W2024402527 hasConcept C127313418 @default.
• W2024402527 hasConcept C127413603 @default.
• W2024402527 hasConcept C17409809 @default.
• W2024402527 hasConcept C191897082 @default.
• W2024402527 hasConcept C192562407 @default.
• W2024402527 hasConcept C199289684 @default.
• W2024402527 hasConcept C2776432453 @default.
• W2024402527 hasConcept C42360764 @default.
• W2024402527 hasConcept C69357855 @default.
• W2024402527 hasConcept C88380143 @default.
• W2024402527 hasConcept C97355855 @default.
• W2024402527 hasConceptScore W2024402527C121332964 @default.
• W2024402527 hasConceptScore W2024402527C127313418 @default.
• W2024402527 hasConceptScore W2024402527C127413603 @default.
• W2024402527 hasConceptScore W2024402527C17409809 @default.
• W2024402527 hasConceptScore W2024402527C191897082 @default.
• W2024402527 hasConceptScore W2024402527C192562407 @default.
• W2024402527 hasConceptScore W2024402527C199289684 @default.
• W2024402527 hasConceptScore W2024402527C2776432453 @default.
• W2024402527 hasConceptScore W2024402527C42360764 @default.
• W2024402527 hasConceptScore W2024402527C69357855 @default.
• W2024402527 hasConceptScore W2024402527C88380143 @default.
• W2024402527 hasConceptScore W2024402527C97355855 @default.
• W2024402527 hasIssue "3-4" @default.
• W2024402527 hasLocation W20244025271 @default.
• W2024402527 hasOpenAccess W2024402527 @default.
• W2024402527 hasPrimaryLocation W20244025271 @default.
• W2024402527 hasRelatedWork W13650140 @default.
• W2024402527 hasRelatedWork W1902620687 @default.
• W2024402527 hasRelatedWork W1985102337 @default.
• W2024402527 hasRelatedWork W1989629536 @default.
• W2024402527 hasRelatedWork W1998251408 @default.
• W2024402527 hasRelatedWork W2313144619 @default.
• W2024402527 hasRelatedWork W2411167658 @default.
• W2024402527 hasRelatedWork W2735903781 @default.
• W2024402527 hasRelatedWork W2889541416 @default.
• W2024402527 hasRelatedWork W2966224558 @default.
• W2024402527 hasVolume "78" @default.
• W2024402527 isParatext "false" @default.

• next