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- W2024402738 abstract "The in-situ synthesis and photophysical properties of a p-hydroxybenzoic acid–terbium (PHBA–Tb3+) complex in sol–gel derived host materials have been investigated. The Raman scattering spectrum of a 1% TbCl3–3% PHBA co-doped gel was the same as that of the PHBA–Tb3+ complex powders synthesized in ethanolic solution, indicating that the PHBA–Tb3+ complex was synthesized in the 1% TbCl3–3% PHBA co-doped gel. The steady-state excitation and emission spectra of the 1% TbCl3–3% PHBA co-doped gel, which were similar to those of the PHBA–Tb3+ complex powders, also indicated the synthesis of the PHBA–Tb3+ complex in the 1% TbCl3–3% PHBA co-doped gel. The time-resolved spectra of the 1%TbCl3–3% PHBA co-doped gel indicated an efficient ligand-to-metal energy transfer, which also confirmed the synthesis of the PHBA–Tb3+ complex in the gel. The luminescence decay curve of the 1% TbCl3–3% PHBA co-doped gel could be fitted by a double-exponential function. Due to the less efficient non-radiative 5D4 relaxation processes in the gel, the presence of the PHBA–Tb3+ complex in the gel led to greatly increased 5D4 lifetimes." @default.
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- W2024402738 date "2002-01-01" @default.
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- W2024402738 title "The in-situ synthesis process and luminescence behavior of a p-hydroxybenzoic acid–terbium complex in sol–gel derived host materials" @default.
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- W2024402738 doi "https://doi.org/10.1039/b205055b" @default.
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