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- W2024408916 abstract "This chapter explains that the potential growth of the chemistry of heterocycles prophesied in 1970 was exploited so vigorously that in almost a decade, it needed a multivolume treatise to comprehend their phenomenal advances. For synthetic organic chemists, an aspect of immense relevance was the synthetic utility of heterocycles as precursors, reagents, vehicles, and transient intermediates. A unique mode of designing heterocyclic reagents and catalysts for achieving the targeted synthetic aims was the development of structurally simpler synthetic models of coenzymes that could imitate the highly efficient biological reactions of these cofactors in a synthetically useful manner. The structural designs of these coenzyme models were rationally based on the physicochemical character of the active participating heterocyclic components of the coenzymes. Thus, thiazolium cations and their analogs, as models of thiamine, catalyze many acyloin and related reactions that could not be achieved by the traditional catalysts." @default.
- W2024408916 created "2016-06-24" @default.
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- W2024408916 date "2006-01-01" @default.
- W2024408916 modified "2023-09-23" @default.
- W2024408916 title "Coenzyme 5,10-Methylene and Methenyltetrahydrofolate Models in Organic Synthesis" @default.
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- W2024408916 doi "https://doi.org/10.1016/s0065-2725(06)91003-4" @default.
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