FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2024415055> ?p ?o ?g. }

• W2024415055 endingPage "296" @default.
• W2024415055 startingPage "261" @default.
• W2024415055 abstract "ABSTRACT The extracting properties of substituted diamides were investigated. The auto-association of N,N'-dimethyl dibutyl tetradecyl malonamide (DMDBTDMA) : (C4H9(CH3)NCO)2CHC14H29 in benzene and in TPH (aliphatic hydrocarbon) was shown by NMR using mass-action model. The degree of aggregation depends on the diluent, the diamide concentration and the acidity. The extraction of HNO3 and HClO4 was investigated by distribution measurements and IR spectroscopy. HNO3 extraction is explained by the competing formation of four adducts : whose the equilibrium constants for 0,72 mol.l-1 amide in TPH are 0.167, 0.215, 5.19-10-3 and 3.7-10-4, respectively, on a molal scale. HClO4 is extracted by a reaction involving the competing formation of the two adducts . Their equilibrium constants for 0.697 mol.1-1 amide in TPH are 0.649 and 1.71, respectively, on a molal scale. V(C=O) IR absorption shifts indicate that in are linked by hydrogen bonds, whereas in is transferred from one molecule of acid to one C=O of the DMDBTDMA. The different behavior of HClO4 and HNO3 can be attributed to their different acid strength, HClO4 being a much stronger acid than HNO3. The proton transfer from HNO3 to the diamide depends on the dielectric constant of the organic medium, the higher values being favourable to ion-pair formation. Oxalic acid is only weakly extracted by DMDBTDMA." @default.
• W2024415055 created "2016-06-24" @default.
• W2024415055 creator A5025825602 @default.
• W2024415055 creator A5081189276 @default.
• W2024415055 creator A5086988856 @default.
• W2024415055 date "1994-03-01" @default.
• W2024415055 modified "2023-09-23" @default.
• W2024415055 title "EXTRACTION BY N,N,N',N-TETRAALKYL -2 ALKYL PROPANE -1,3 DIAMIDES. I. H₂O, HNO₃and HClO₄" @default.
• W2024415055 cites W1984183726 @default.
• W2024415055 cites W1984654871 @default.
• W2024415055 cites W1985891122 @default.
• W2024415055 cites W1992272199 @default.
• W2024415055 cites W2008892731 @default.
• W2024415055 cites W2017384220 @default.
• W2024415055 cites W2034042541 @default.
• W2024415055 cites W2038640310 @default.
• W2024415055 cites W2039543386 @default.
• W2024415055 cites W2042216459 @default.
• W2024415055 cites W2044361381 @default.
• W2024415055 cites W2047823835 @default.
• W2024415055 cites W2078070099 @default.
• W2024415055 cites W2085127616 @default.
• W2024415055 cites W2095367979 @default.
• W2024415055 cites W2101820242 @default.
• W2024415055 cites W2103701331 @default.
• W2024415055 cites W2123664532 @default.
• W2024415055 cites W2156347272 @default.
• W2024415055 doi "https://doi.org/10.1080/07366299408918211" @default.
• W2024415055 hasPublicationYear "1994" @default.
• W2024415055 type Work @default.
• W2024415055 sameAs 2024415055 @default.
• W2024415055 citedByCount "96" @default.
• W2024415055 countsByYear W20244150552012 @default.
• W2024415055 countsByYear W20244150552013 @default.
• W2024415055 countsByYear W20244150552014 @default.
• W2024415055 countsByYear W20244150552015 @default.
• W2024415055 countsByYear W20244150552016 @default.
• W2024415055 countsByYear W20244150552017 @default.
• W2024415055 countsByYear W20244150552018 @default.
• W2024415055 countsByYear W20244150552019 @default.
• W2024415055 countsByYear W20244150552020 @default.
• W2024415055 countsByYear W20244150552021 @default.
• W2024415055 countsByYear W20244150552022 @default.
• W2024415055 countsByYear W20244150552023 @default.
• W2024415055 crossrefType "journal-article" @default.
• W2024415055 hasAuthorship W2024415055A5025825602 @default.
• W2024415055 hasAuthorship W2024415055A5081189276 @default.
• W2024415055 hasAuthorship W2024415055A5086988856 @default.
• W2024415055 hasConcept C10710636 @default.
• W2024415055 hasConcept C108204754 @default.
• W2024415055 hasConcept C112887158 @default.
• W2024415055 hasConcept C113196181 @default.
• W2024415055 hasConcept C13965031 @default.
• W2024415055 hasConcept C145148216 @default.
• W2024415055 hasConcept C147789679 @default.
• W2024415055 hasConcept C155647269 @default.
• W2024415055 hasConcept C168191866 @default.
• W2024415055 hasConcept C16946580 @default.
• W2024415055 hasConcept C175804951 @default.
• W2024415055 hasConcept C178790620 @default.
• W2024415055 hasConcept C179104552 @default.
• W2024415055 hasConcept C184651966 @default.
• W2024415055 hasConcept C185592680 @default.
• W2024415055 hasConcept C2777691172 @default.
• W2024415055 hasConcept C2778439535 @default.
• W2024415055 hasConcept C2780263894 @default.
• W2024415055 hasConcept C2781346138 @default.
• W2024415055 hasConcept C32909587 @default.
• W2024415055 hasConcept C4725764 @default.
• W2024415055 hasConceptScore W2024415055C10710636 @default.
• W2024415055 hasConceptScore W2024415055C108204754 @default.
• W2024415055 hasConceptScore W2024415055C112887158 @default.
• W2024415055 hasConceptScore W2024415055C113196181 @default.
• W2024415055 hasConceptScore W2024415055C13965031 @default.
• W2024415055 hasConceptScore W2024415055C145148216 @default.
• W2024415055 hasConceptScore W2024415055C147789679 @default.
• W2024415055 hasConceptScore W2024415055C155647269 @default.
• W2024415055 hasConceptScore W2024415055C168191866 @default.
• W2024415055 hasConceptScore W2024415055C16946580 @default.
• W2024415055 hasConceptScore W2024415055C175804951 @default.
• W2024415055 hasConceptScore W2024415055C178790620 @default.
• W2024415055 hasConceptScore W2024415055C179104552 @default.
• W2024415055 hasConceptScore W2024415055C184651966 @default.
• W2024415055 hasConceptScore W2024415055C185592680 @default.
• W2024415055 hasConceptScore W2024415055C2777691172 @default.
• W2024415055 hasConceptScore W2024415055C2778439535 @default.
• W2024415055 hasConceptScore W2024415055C2780263894 @default.
• W2024415055 hasConceptScore W2024415055C2781346138 @default.
• W2024415055 hasConceptScore W2024415055C32909587 @default.
• W2024415055 hasConceptScore W2024415055C4725764 @default.
• W2024415055 hasIssue "2" @default.
• W2024415055 hasLocation W20244150551 @default.
• W2024415055 hasOpenAccess W2024415055 @default.
• W2024415055 hasPrimaryLocation W20244150551 @default.
• W2024415055 hasRelatedWork W1971527124 @default.
• W2024415055 hasRelatedWork W2012593649 @default.
• W2024415055 hasRelatedWork W2324898221 @default.
• W2024415055 hasRelatedWork W2351057607 @default.

• next