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- W2024421792 abstract "Abstract The initiation and propagation reactions in anionic non‐equilibrium polymerization of octamethylcyclotetrasiloxane (D 4 ) initiated by silazyl‐lithiums are investigated. It is found that: both the steric hindrance effect and the electronic effect of the substitutes on the Si atom Si influences the initiation activity of silazyl‐lithiums; temperature effect on the propagation rate of D 4 increases strongly above 40 °C; the molecular weight distribution of the prepared polysiloxanes widens with time. © 2003 Society of Chemical Industry" @default.
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- W2024421792 date "2004-01-15" @default.
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- W2024421792 title "Anionic non-equilibrium ring-opening polymerization of octamethylcyclotetrasiloxane(D4) initiated by silazyl-lithiums" @default.
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